Notes
Slide Show
Outline
1
PRECIPITATION REACTIONS
  • There are 6 classifications of reactions:
  • Combustion
  • Oxidation-reduction
  • Synthesis
  • Decomposition
  • Single displacement
  • Double displacement


2
IONIC REACTIONS
  • Reactions that involve the dissociation of ions are called ionic reactions.
  • Most of these are a double displacement type.
  • These reactions take place in water but the water does not take part in the reaction.  Water is the medium of occurrence
3
EQUATIONS
  • Reactions are written with molecular formulas.
  • CaCl2(aq)+K2SO4(aq)àCaSO4(s)+ 2KCl(aq)
  •   From molecular formulas the reacting species can be written as complete ionic equations.




4
COMPLETE IONIC EQUATIONS
  • Complete ionic equations are written to show the dissociated state of the compound:
  • Ca+2(aq) +2Cl-(aq) + 2K+(aq)+SO4-2(aq) àCaSO4(s)+2K+(aq) +2Cl-(aq)



5
COMPLETE IONIC EQUATIONS
  • The physical states are included as subscripts.  The symbol (aq) means that the compound is not only dissolved in water but the ions are already separated in solution.
  • Formulas for insoluble compounds are not separated.  The ions of water insoluble compounds are immobile (CaSO4)
6
COMPLETE IONIC EQUATIONS
  • The equations must be balanced for number of atoms and charge.
  • The equation must be electrically neutral.
7
NET IONIC EQUATIONS
  • Net ionic equations are written to express only the ions involved in forming the precipitate.
  • If an ion appears on both sides of the equation but does not take part in forming the precipitate, it is called a spectator and is cancelled from the equation.
  • Be sure cancelled species are in the same physical state
8
NET IONIC EQUATIONS
  • When all the spectator ions are cancelled, the remaining ions and the precipitate are written as the net ionic equation.
  • Ca+2(aq) +2Cl-(aq) + 2K+(aq)+SO4-2(aq) àCaSO4(s)+2K+(aq) +2Cl-(aq)
  • Net Ionic Equation:
  • Ca+2(aq) + SO4-2(aq) à CaSO4(s)